12.1 Gas Pressure
Gases exert pressure, which is force per unit area. The pressure of a gas may be expressed in the SI unit of pascal or kilopascal, as well as in many other units including torr, atmosphere, and bar. Atmospheric pressure is measured using a barometer; other gas pressures can be measured using one of several types of manometers.
12.2 Relating Pressure, Volume, Amount, and Temperature: The Ideal Gas Law
The behaviour of gases can be described by several laws based on experimental observations of their properties. The pressure of a given amount of gas is directly proportional to its absolute temperature, provided that the volume does not change (Amonton’s / Gay-Lussac’s law). The volume of a given gas sample is directly proportional to its absolute temperature at constant pressure (Charles’ law). The volume of a given amount of gas is inversely proportional to its pressure when temperature is held constant (Boyle’s law). Under the same conditions of temperature and pressure, equal volumes of all gases contain the same number of molecules (Avogadro’s law).
The equations describing these laws are special cases of the ideal gas law, PV = nRT, where P is the pressure of the gas, V is its volume, n is the number of moles of the gas, T is its kelvin temperature, and R is the ideal (universal) gas constant.
12.3 Effusion and Diffusion of Gases
Gaseous atoms and molecules move freely and randomly through space. Diffusion is the process whereby gaseous atoms and molecules are transferred from regions of relatively high concentration to regions of relatively low concentration. Effusion is a similar process in which gaseous species pass from a container to a vacuum through very small orifices. The rates of effusion of gases are inversely proportional to the square roots of their densities or to the square roots of their atoms/molecules’ masses (Graham’s law).
12.4 Stoichiometry of Gaseous Substances, Mixtures, and Reactions
The ideal gas law can be used to derive a number of convenient equations relating directly measured quantities to properties of interest for gaseous substances and mixtures. Appropriate rearrangement of the ideal gas equation may be made to permit the calculation of gas densities and molar masses. Dalton’s law of partial pressures may be used to relate measured gas pressures for gaseous mixtures to their compositions. Avogadro’s law may be used in stoichiometric computations for chemical reactions involving gaseous reactants or products.
12.5 The Kinetic-Molecular Theory
The kinetic molecular theory is a simple but very effective model that effectively explains ideal gas behaviour. The theory assumes that gases consist of widely separated molecules of negligible volume that are in constant motion, colliding elastically with one another and the walls of their container with average speeds determined by their absolute temperatures. The individual molecules of a gas exhibit a range of speeds, the distribution of these speeds being dependent on the temperature of the gas and the mass of its molecules.
12.6 Non-Ideal Gas Behaviour
Gas molecules possess a finite volume and experience forces of attraction for one another. Consequently, gas behaviour is not necessarily described well by the ideal gas law. Under conditions of low pressure and high temperature, these factors are negligible, the ideal gas equation is an accurate description of gas behaviour, and the gas is said to exhibit ideal behaviour. However, at lower temperatures and higher pressures, corrections for molecular volume and molecular attractions are required to account for finite molecular size and attractive forces. The van der Waals equation is a modified version of the ideal gas law that can be used to account for the non-ideal behaviour of gases under these conditions.