Appendix H | Ionization Constants of Weak Acids

Ionization Constants of Weak Acids

Acid

Formula

Ka at 25°C

Lewis Structure1

acetic

CH3COOH

1.75 × 10-5

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arsenic

H3AsO4

5.5 × 10-3

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H2AsO4

1.7 × 10-7

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HAsO42-

5.1 × 10-12

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arsenous

H3AsO3

5.1 × 10-10

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benzoic

C6H5COOH

6.25 × 10-5

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boric

H3BO3

5.4 × 10-10

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H2BO3

1 × 10-14 *

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carbonic

H2CO3

4.5 × 10-7

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HCO3

4.7 × 10-11

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chlorous

HClO2

1.1 × 10-2

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cyanic

HOCN

3.5 × 10-4

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formic

HCOOH

1.8 × 10-4

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hydrazoic

HN3

2 × 10-5

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hydrocyanic

HCN

6.2 × 10-10

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hydrofluoric

HF

6.3 × 10-4

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hydrogen peroxide

H2O2

2.4 × 10-12

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hydrogen selenide

H2Se

1.3 × 10-4

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HSe

1.0 × 10-11

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hydrogen sulfide

H2S

8.9 × 10-8

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HS

1 × 10-19

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hydrogen telluride

H2Te

2 × 10-3

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HTe

1 × 10-11

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hypobromous

HOBr

2.8 × 10-9

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hypochlorous

HOCl

4.0 × 10-8

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nitrous

HNO2

5.6 × 10-4

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oxalic

H2C2O4

5.6 × 10-2

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HC2O4

1.5 × 10-4

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phenol

C5H5OH

1.0 × 10-10

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phosphoric

H3PO4

6.9 × 10-3

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H2PO4

6.2× 10-8

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HPO42-

4.8 × 10-13

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phosphorous

H3PO3

5 × 10-2

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H2PO3

2.0 × 10-7

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sulfuric

H2SO4

strong acid

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HSO4

1.0 × 10-2

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sulfurous

H2SO3

1.4 × 10-2

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HSO3

6 × 10-8

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1 Hydrogen atom indicated in red represents the donated proton in an acid-base reaction.

* Represents the lower limit value.

REFERENCES

1. “Dissociation Constants of Inorganic Acids and Bases” in CRC Handbook of Chemistry and Physics, 100th Edition (Internet Version 2019), John R. Rumble, ed., CRC Press/Taylor & Francis, Boca Raton, FL.

2. “Dissociation Constants of Organic Acids and Bases” in CRC Handbook of Chemistry and Physics, 100th Edition (Internet Version 2019), John R. Rumble, ed., CRC Press/Taylor & Francis, Boca Raton, FL.

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