# 19 Appendix 8: Atomic orbitals.

The overall atomic orbital for any one electron can be symbolized as . This function incorporates all the features we discussed when talking spherical harmonics. The function can be written as a product of two parts. The function can be written in Cartesian space as we are familiar with but a mathematically simpler way to write it is in polar coordinates, . In this polar coordinate space, we can still represent the full 3d space but now, any nodes that depend on the radius (spherical shaped nodes) can be expressed as simply the value of where the functions crosses zero. similarly, by expressing the wave functions in polar coordinates, we will be using sines and cosines of those angles. Since sines and cosines cross zero, we will have the angular notes described. The relation ship between polar coordinates and Cartesian coordinates can be seen in the following diagram.

So, we can write the atomic orbital in terms of cartesian coordinates or in polar coordinates . Now that we have the function in polar coordinates, we can rewrite the overall wave function as the product of two functions, a radial part shows how the functions vary with the distance, , from the nucleus and the angular part shows how the function varies with angles and .

This is actually a common mathematical technique called separation of variables. It allows us in this case to more easily visualize how the functions vary with radius (the radial function) and with angle (the angular function). The functions tend to zero as the radial distance tends to zero. That is represented in the reverse exponential part of the radial function for any orbital. You will see something like in all the radial functions. This is a generic reverse exponential where the value goes to zero as goes to infinity.

Note:

That table looks a bit daunting at first glance but with a bit of thought, it is not that hard to understand. The first take-a-way is that those orbitals are simply math functions. They don’t have anything in them that is truly incomprehensible. Let’s look at a few examples and see how these equations work.

### Consider the 1s orbital.

Notice that there is only one angular function for all orbitals. it is simply a constant. there is no angular dependence for an orbital. All orbitals are spherical. Notice the radial part of the function. It has two parts. The constant in front of the exponential and the exponential decay part . The constant in front, along with the constant in the angular part together are called the normalization factor. This is to make sure the orbital is exactly the right size to hole 1 electron. When integrated over 3-space, the result is 1, i.e., one electron exactly fits in each orbital. The exponential decay, as described above means the orbital tends to zero as the distance from the nucleus becomes zero. If you square the wave function, you will get the electron probability function. So another way of saying this is as the radial distance increases to infinity, the probability of finding the electron goes to zero.

### 2s orbital

Now, let’s consider a slightly more complicated orbital, a orbital. This one has so there are no radial nodes (remember, quantum number is the number of angular nodes), that means the one node in the orbital must be radial (spherical). We expect to see the function go through zero and change phase at a certain distance (at the node). Looking at the radial part of the function, you see some constants again, which we can ignore as just part of normalization. You can see the exponential decay term just as you saw in the orbital. What’s new is the parenthetical term . This term will make the whole function go to zero when . Now look at the simulation of the orbital.

So, we can make up any orbital we want by combining the correct combination of angular and radial parts from the table above.

### 2p_{z} orbital

Let’s make an orbital with an angular node rather than a radial node. The function is the simplest orbital that has an angular node. Let’s make a function; you make it by multiplying the angular with the radial part.

Note that the radial part has only the exponential decay part. There are no parts of this radial function that go to zero. The angular part of the function has a in it; anywhere that is zero, the whole function will go to zero. Since the cosine function passes through zero at (aka 90°), this means the node will be in the plane. Look at this projection of the orbital, looking down the axis with the axis vertical.

So, we have seen a radial node and an angular nodes and seen the functions that have defined them in our math. We can imagine that any orbital can be described using this kind of function, except that as the number of nodes increases, the math would get more complicated.

### 3d(xy) orbital

Let’s try something a bit more complicated; a function. Notice that all the 3d functions have the same radial part, so we just choose the correct angular part and multiply it to the radial part.

This orbital, like all the others has a normalization constant. It tails off to zero as the distance goes to infinity. But this one has angular nodes. there are sine and cosine functions and you know that these pass through zero once as you go around the unit circle. The particular combination of angular functions in the 3d(xy) orbital gives us this shape. Note that there are no left-over spherical nodes; n=3 means 2 nodes. means they are both angular (planar in this case).

### 3p_{z} orbital

OK, One last orbital. This one also with two nodes. So it must be an function. This one has one angular node (so ; a p orbital) and one radial node. This function will look similar to the 2p function above but you will also be able to see the radial node in addition to the angular planar node.

Finally, to make up the entire wave function for a multi-electron atom, you would multiply one complete orbital for each electron in the atom into an overall wave function for the entire atom.

In theory, you would be able to do this for multi-atomic species, multiplying all the atomic orbitals on all the atoms together, with proper adjustments of the normalization factors, to make new molecular orbitals. But that is a process for an upper-year class.

Once you have a wave function for your species, you use the Schrödinger equation to get out the array of energies .

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