14 Ions and Ionic Compounds

So far, we have discussed elements and compounds that are electrically neutral. They have the same number of electrons as protons, so the negative charges of the electrons is balanced by the positive charges of the protons. However, this is not always the case. Electrons can move from one atom to another; when they do, species with overall electric charges are formed. Such species are called ions. Species with overall positive charges are termed cations, while species with overall negative charges are called anions. Remember that ions are formed only when electrons move from one atom to another; a proton never moves from one atom to another. Compounds formed from positive and negative ions are called ionic compounds.

Individual atoms can gain or lose electrons. When they do, they become monatomic ions. When atoms gain or lose electrons, they usually gain or lose a characteristic number of electrons and so take on a characteristic overall charge. Table 3.6 “Monatomic Ions of Various Charges” lists some common ions in terms of how many electrons they lose (making cations) or gain (making anions). There are several things to notice about the ions in Table 3.6 “Monatomic Ions of Various Charges”. First, each element that forms cations is a metal, except for one (hydrogen), while each element that forms anions is a nonmetal. This is actually one of the chemical properties of metals and nonmetals: metals tend to form cations, while nonmetals tend to form anions. Second, most atoms form ions of a single characteristic charge. When sodium atoms form ions, they always form a 1+ charge, never a 2+ or 3+ or even 1− charge. Thus, if you commit the information in Table 3.6 “Monatomic Ions of Various Charges” to memory, you will always know what charges most atoms form. (In Chapter 9 “Chemical Bonds”, we will discuss why atoms form the charges they do.)

Third, there are some exceptions to the previous point. A few elements, all metals, can form more than one possible charge. For example, iron atoms can form 2+ cations or 3+ cations. Cobalt is another element that can form more than one possible charged ion (2+ and 3+), while lead can form 2+ or 4+ cations. Unfortunately, there is little understanding which two charges a metal atom may take, so it is best to just memorize the possible charges a particular element can have.

Note the convention for indicating an ion. The magnitude of the charge is listed as a right superscript next to the symbol of the element. If the charge is a single positive or negative one, the number 1 is not written; if the magnitude of the charge is greater than 1, then the number is written before the + or − sign. An element symbol without a charge written next to it is assumed to be the uncharged atom.

Naming an ion is straightforward. For a cation, simply use the name of the element and add the word ion (or if you want to be more specific, add cation) after the element’s name. So Na⁺ is the sodium ion; Ca²⁺ is the calcium ion. If the element has more than one possible charge, the value of the charge comes after the element name and before the word ion. Thus, Fe²⁺ is the iron two ion, while Fe³⁺ is the iron three ion. In print, we use roman numerals in parentheses to represent the charge on the ion, so these two iron ions would be represented as the iron(II) cation and the iron(III) cation, respectively.

For a monatomic anion, use the stem of the element name and append the suffix -ide to it, and then add ion. This is similar to how we named molecular compounds. Thus, Cl⁻ is the chloride ion, and N³⁻ is the nitride ion.

Chemical formulas for ionic compounds are called ionic formulas. A proper ionic formula has a cation and an anion in it; an ionic compound is never formed between two cations only or two anions only. The key to writing proper ionic formulas is simple: the total positive charge must balance the total negative charge. Because the charges on the ions are characteristic, sometimes we have to have more than one of a cation or an anion to balance the overall positive and negative charges. It is conventional to use the lowest ratio of ions that are needed to balance the charges.

For example, consider the ionic compound between Na⁺ and Cl⁻. Each ion has a single charge, one positive and one negative, so we need only one ion of each to balance the overall charge. When writing the ionic formula, we follow two additional conventions: (1) write the formula for the cation first and the formula for the anion next, but (2) do not write the charges on the ions. Thus, for the compound between Na⁺ and Cl⁻, we have the ionic formula NaCl (Figure 3.5 “NaCl = Table Salt”). The formula Na₂Cl₂ also has balanced charges, but the convention is to use the lowest ratio of ions, which would be one of each. (Remember from our conventions for writing formulas that we don’t write a 1 subscript if there is only one atom of a particular element present.) For the ionic compound between magnesium cations (Mg²⁺) and oxide anions (O²⁻), again we need only one of each ion to balance the charges. By convention, the formula is MgO.

Figure 3.5 NaCl = Table Salt